2-(3-Ethylsulfanyl-5-phenyl-1-benzofuran-2-yl)acetic acid
نویسندگان
چکیده
The title compound, C(18)H(16)O(3)S, crystallizes with two symmetry-independent mol-ecules in the asymmetric unit. The phenyl rings are rotated out of the benzofuran planes, making dihedral angles of 43.38 (7) and 56.13 (6)° in the two mol-ecules. The carboxyl groups are involved in inversion-related inter-molecular O-H⋯O hydrogen bonds, which link the mol-ecules into centrosymmetric dimers. These dimers are further packed into stacks along the b axis by weak non-classical inter-molecular C-H⋯O hydrogen bonds. The crystal structure also exhibits inter-molecular C-H⋯π inter-actions, and two aromatic π-π inter-actions between the furan rings of neighbouring benzofuran systems; the centroid-centroid distances are 3.500 (3) and 3.605 (3) Å.
منابع مشابه
2-(3-Ethylsulfanyl-5-fluoro-1-benzofuran-2-yl)acetic acid
The title compound, C(12)H(11)FO(3)S, was prepared by alkaline hydrolysis of ethyl 2-(3-ethyl-sulfan-yl-5-fluoro-1-benzofuran-2--yl) acetate. In the crystal structure, the carboxyl groups are involved in inter-molecular O-H⋯O hydrogen bonds, which link the mol-ecules into centrosymmetric dimers. These dimers are further packed into stacks along the b axis by aromatic π-π inter-actions between t...
متن کامل3-Ethylsulfanyl-2-(4-fluorophenyl)-5-phenyl-1-benzofuran
In the title compound, C(22)H(17)FOS, the crystal studied was an inversion twin with a 0.42 (18):0.58 (18) domain ratio. The 4-fluoro-phenyl ring is rotated out of the benzofuran plane, making a dihedral angle of 17.82 (6)°, and the dihedral angle between the 5-phenyl ring and the benzofuran plane is 29.45 (7)°.
متن کامل3-Ethylsulfanyl-2,5-diphenyl-1-benzofuran
In the title compound, C(22)H(18)OS, the 2-phenyl ring is rotated out of the benzofuran plane, making a dihedral angle of 29.18 (6)°. The dihedral angle between the 5-phenyl ring and the benzofuran plane is 20.42 (5)°. In the crystal structure, mol-ecules are linked by weak inter-molecular C-H⋯π inter-actions.
متن کامل2-(5-Fluoro-3-isopropylsulfanyl-7-methyl-1-benzofuran-2-yl)acetic acid
The title compound, C(14)H(15)FO(3)S, was prepared by alkaline hydrolysis of ethyl 2-(5-fluoro-3-isopropyl-sulfanyl-7-methyl-1-benzofuran-2-yl)acetate. In the crystal, mol-ecules are linked via pairs of O-H⋯O hydrogen bonds, forming inversion dimers. These dimers are connected by weak C-H⋯O hydrogen bonds.
متن کامل2-(5-Fluoro-7-methyl-3-methylsulfanyl-1-benzofuran-2-yl)acetic acid
The title compound, C(12)H(11)FO(3)S, was prepared by alkaline hydrolysis of ethyl 2-(5-fluoro-7-methyl-3-methyl-sulfanyl-1-benzofuran-2-yl)acetate. In the crystal, the carboxyl groups are involved in inter-molecular O-H⋯O hydrogen bonds, which link the mol-ecules into centrosymmetric dimers.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009